Safety Data Sheet

According to GHS (Global Harmonized System) - Hazcom 2012
Date Printed (YYYY-MM-DD): 2018-01-31 

Section 1 - Product and Company Information

Product Name: Cream Hardener
Product Part Number(s): 1046-H
Recommended Use: Hardener for polyester filler.
Revision Date (YYYY-MM-DD):

COMPANY IDENTIFICATION:EMERGENCY TELEPHONE NUMBER
Polyvance24 Hour Emergency ContactChemtrec - 1-800-424-9300 (Outside USA 703-527-3887)
1128 Kirk Rd.Customer Information Number256-638-4103 (7AM - 4PM (CST) M-F)
Rainsville, AL 35986
Information Email: info@polyvance.com

Section 2 - Hazards Identification

Appearance:Red paste
Odor:Ester-type odor
Hazard Statement:
 DANGER! Heating may cause a fire or explosion. Causes skin irritation. May cause an allergic skin reaction. Causes eye irritation.  

Signal Word:  

DANGER!
Signal Word Hazard:   Heating may cause a fire or explosion
GHS Physical Hazard PictogramsGHS Health Hazard PictogramsGHS Environmental Hazard Pictograms
Not Applicable

Irritant
 
Not Applicable

GHS Hazards Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
Physical H241 Heating may cause a fire or explosion
Health H315 Causes skin irritation
Health H317 May cause an allergic skin reaction
Health H320 Causes eye irritation
Precautionary Statement:
 Keep out of reach of children. Read label before use. Do not get in eyes, on skin, or on clothing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.  

GHS Precautionary Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
General P102 Keep out of reach of children
General P103 Read label before use
Prevention P262 Do not get in eyes, on skin, or on clothing
Response P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting

Potential Health Effects

Eye Contact:Eye irritant.
 
Skin Contact:Prolonged exposure may cause skin irritation.
 
Skin Absorption:Prolonged skin contact is unlikely to result in absorption of harmful amounts.
 
Inhalation:Brief exposure (minutes) is not likely to cause adverse effects. Excessive exposure may cause irritation to upper respiratory tract (nose and throat).
 
Ingestion:Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause injury.
 

Section 3 - Composition/Information on Ingredients

Component CAS # ENIECS REACH Reg. No. Amount
 
Benzoyl Peroxide 94-36-0 47 - 50%
Calcium Carbonate 471-34-1 15 - 19%
Fumed Silica 7631-86-9 0 - 4%
Plasticizer (Proprietary, Ester based, non-Pthalate) 800951-5002-p 25 - 30%
Surfactant (Proprietary, Ethoxylated Alkyl Phenol) 800951-5003-p 1 - 4%
Water 7732-18-5 10-13%

Section 4 - First Aid Measures

Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
 
Skin Contact: Flush with plenty of soap and water for 15 minutes.
 
Inhalation: Remove to fresh air immediately. Give CPR/Oxygen if necessary.
 
Ingestion: Give patient several glasses of water, but do not induce vomiting; seek immediate medical attention.
 

Section 5 - Firefighting Measures

Extinguishing Media: Carbon dioxide, dry chemical, foam
 
Fire Fighting Procedures: Fight like a fuel oil fire. Cool fire exposed containers with water spray. Fire fighter should wear OSHA/NIOSH approved self-contained breathing apparatus. For large quantities, fight fire from a distance.
 
Special Protective Equipment for Firefighters: Firefighting personnel should be equipped with insulated, autonomous respiratory protection equipment.
 
Unusual Fire and Explosion Hazards: Closed containers exposed to high temperatures, such as fire conditions may rupture.
 

Section 6 - Accidental Release Measures

Steps to be Taken if Material is Released or Spilled: Wash and clean up small spills with water and detergent. Pick up large spills with inert absorbent and place in container for disposal.
 
Personal Precautions: Ventilation: General ventilation is required during normal use. Protective gloves: Wear appropriate impervious gloves to prevent skin contact. Eye proctection: Wear protective safety glasses with side-shields or face shield. Other protection: Wear appropriate clothing to prevent skin contact.
 
Environmental Precautions:
 

Section 7 - Handling and Storage

General Handling: Avoid inhalation of dusts created during machining. Inform personnel of risks associated with the product, the precautions to be taken and procedures to follow where an accident occurs. Observe personal hygiene rules to avoid contact with eyes and skin. Avoid inhaling vapors produced by the material, especially when heated and/or sprayed. Install showers and eye baths. Ensure sufficient ventilation, including appropriate local air extraction, in order to comply with workplace exposure limits. Where vapors could escape into the air, local specific means of ventilation will be necessary. Wash hands thoroughly at beginning of every work break and at the end of the working day. Work stations and the general working area must be kept perfectly clean. Avoid exposure to the material of person having suffered from eczema or any other skin condition.
 
Other Precautions:
 
Storage: Do not store the product above 100F (38C). Keep product away from heat, open flame, and other sources of ignition. Avoid contact with strong acids, alkali's and oxidizers. Do not freeze- separation may occur upon thawing. Cream hardener has an 18 month shelf life.
 

Section 8 - Precautions to Control Exposure / Personal Protection

ComponentSourceTypeValueRemarks

Personal Protective Equipment (PPE):

Eye/Face Protection: Safety glasses or goggles with splash guards or rubber gloves.
 
Skin Protection: To prevent prolonged exposure, use rubber gloves.
 
Respiratory Protection: Does not require a respirator with general room ventilation. If room ventilation is lacking, use NIOSH/MSHA approved respirator to remove vapors. Use an air supplied respirator if necessary.
 
Hygenic Measures: Wash hands before smoking, eating or using washroom.
 
Other Protection Measures: Wear protective clothing as required to prevent skin contact.
 
Engineering Controls: Use adequate ventilation in volume and pattern to keep TLV/PEL below recommended levels. General mechanical ventilation is acceptable.
 


Section 9 - Physical and Chemical Properties

Appearance: Red Paste
 
Color: Red
 
ph: Not determined
 
Flash Point: 184°F (84°C)
 
Upper Flammable Limit: Not available
 
Lower Flammable Limit: Not available
 
Autoignition Temperature: Not available
 
Vapor Pressure: 0.67 - 0.93 kPa
 
Boiling Point: Benzoyl Peroxide decomposes explosively above 55C
 
Vapor Density: Heavier than air
 
Specific Gravity: 1.2 - 1.3
 
Freezing Point: Not available
 
Melting Point: Not available
 
Solubility in Water: Negligible
 
Evaporation Rate: Not available
 
Partition Coefficient: Not available
 
Decomposition Temperature: 55°C (131°F)
 
Visosity: Not available

Section 10 - Stability and Reactivity

Stability/Instability: Not Stable
 
Conditions To Avoid: Open flames, sparks, heat, electrical and static discharge.
 
Incompatible Materials: Strong acids, alkalis, oxidizers, reducing agents, mineral acids, metal salt (catalyst)
 
Hazardous Polymerization: Will Not Occur
 
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, carbon and possibly flammable gasses.
 

Section 11 - Toxicological Information

Ingestion Toxicity: Low toxicity for a single oral dose. LD50 (rat): >5000 mg/kg
Skin Absorption:Repeated or prolonged single exposure may cause irritation to the skin. May cause a cutaneous allergic reaction in predisposed individuals. It appears unlikely that any danger is attached to absorption of quantities of the product through the skin following prolonged single exposure.
Inhalation
May be irritating to the respiratory tract. LC50 (rat): > 24.3 mg/L
 
Eye Irritation
Causes eye irritation
 
Skin Irritation
May cause allergic skin reaction.
 

Section 12 - Ecological Information

Movement & Partitioning
Not Available
 
Persistence and Degradability
Not Available
 
ECOTOXICITY
Not established
 
Bioaccumulation:
Not Available
 

Section 13 - Disposal Considerations

Disposal Method:
Dispose of in accordance with local, state, and federal regulations. Do not incinerate in closed containers
 
Container Disposal: Disposal must be made according to official regulations.
 

Section 14 - Transport Information

DOT

Proper Shipping Name: Organic Peroxide Type E., Solid (35% Dibenzoyl Peroxide)
 
Hazard Class: 5.2
 
ID Number: UN3108
 
Packing Group: II
 

IMDG (Maritime transport)

IMDG Class: 5.2
 
UN Number: UN3108
 
Label: H0072000
 
Packaging Group: II
 
EMS Number: F-J, S-R
 
Proper Shipping Name: Organic Peroxide Type E., Solid (Dibenzoyl Peroxide)
 

Section 15 - Regulatory Information

Superfund Amendments and Reathorization Act of 1986 (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312

The following table list hazardous components and the regulatory lists for which they are required to be reported.

Component: Benzoyl Peroxide
CAS Number: 94-36-0
Amount: 47 - 50%
Benzoyl Peroxide is listed in SARA 313
Benzoyl Peroxide is known to the State of California to cause cancer.
Benzoyl Peroxide is listed with the Environmental Protection Agency (EPA) as a possible carcinogen.
Benzoyl Peroxide is listed with the Occupational Safety and Health Administration (OSHA) as a possible carcinogen.

HMIS Rating (Scale 0 - 4)

HEALTH  2  Health = 2
FIRE  2  Fire = 2
PHYSICAL  1  Physical = 1
PERSONAL PROTECTION G Personal Protection = G

NFPA Ratings

 2 
2 2
Health = 2
Fire = 2
Reactivity =2

Section 16 - Other Information

Legend

DISCLAIMER
This Safety Data Sheet (SDS) is prepared in compliance with GHS Hazcom 2012. The information may be based in part on information provided by component suppliers and is believed to be correct as of the date hereof. However, no warranty or merchantability, fitness for any use, or any other warranty is expressed or is to be implied regarding the accuracy of of this data, the results to be obtained from the use of the material, or the hazards connected with such use. Since the information contained herein my be applied under conditions beyond our control and with which we may be unfamiliar, and since data made available subsequent to the date hereof may suggest modification of the information, we assume no responsibility for the result of its use. This information and material is furnished on the condition that the person receiving it shall make his/her own determination as the the suitability of the material for his/her particular purpose and on the condition that he/she assume the risk of his/her use thereof.