Safety Data Sheet

According to GHS (Global Harmonized System) - Hazcom 2012
Date Printed (YYYY-MM-DD): 2018-01-31 

Section 1 - Product and Company Information

Product Name: Padded Dash Filler
Product Part Number(s): 2050-9
Recommended Use: To repair cracked automobile dashboards
Revision Date (YYYY-MM-DD):

COMPANY IDENTIFICATION:EMERGENCY TELEPHONE NUMBER
Polyvance24 Hour Emergency ContactChemtrec - 1-800-424-9300 (Outside USA 703-527-3887)
1128 Kirk Rd.Customer Information Number256-638-4103 (7AM - 4PM (CST) M-F)
Rainsville, AL 35986
Information Email: info@polyvance.com

Section 2 - Hazards Identification

Appearance:Gray, high-viscosity, liquid
Odor:Pungent
Hazard Statement:
 WARNING! Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. Toxic to aquatic life.  

Signal Word:  

WARNING!
Signal Word Hazard:   Flammable liquid and vapor
GHS Physical Hazard PictogramsGHS Health Hazard PictogramsGHS Environmental Hazard Pictograms

Flammable

Health Hazard
 
Not Applicable

GHS Hazards Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
Physical H226 Flammable liquid and vapor
Health H304 May be fatal if swallowed and enters airways
Health H315 Causes skin irritation
Health H319 Causes serious eye irritation
Health H332 Harmful if inhaled
Health H335 May cause respiratory irritation
Health H372 Causes damage to organs through prolonged or repeated exposure
Environmental H401 Toxic to aquatic life
Precautionary Statement:
 Keep away from heat/sparks/open flames/hot surfaces - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/light/.../equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash ... thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. In case of fire: Use appropriate media for extinction. Store in a well ventilated place. Keep container tightly closed. Dispose of contents/container to appropriate waste site of reclaimer in accordance with local and national regulations..  

GHS Precautionary Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
Prevention P210 Keep away from heat/sparks/open flames/hot surfaces - No smoking
Prevention P233 Keep container tightly closed
Prevention P240 Ground/bond container and receiving equipment
Prevention P241 Use explosion-proof electrical/ventilating/light/.../equipment
Prevention P242 Use only non-sparking tools
Prevention P243 Take precautionary measures against static discharge
Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray
Prevention P264 Wash ... thoroughly after handling
Prevention P271 Use only outdoors or in a well-ventilated area
Prevention P273 Avoid release to the environment
Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection
Response P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
Response P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Response P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Response P312 Call a POISON CENTER or doctor/physician if you feel unwell
Response P332+313 If skin irritation occurs: Get medical advice/attention
Response P370+378 In case of fire: Use appropriate media for extinction
Storage P403+233 Store in a well ventilated place. Keep container tightly closed
Disposal P501 Dispose of contents/container to appropriate waste site of reclaimer in accordance with local and national regulations.

Potential Health Effects

Eye Contact:Irritating to eyes
 
Skin Contact:Contact causes skin irritation. Prolonged skin contact may defat skin and produce dermatitis.
 
Skin Absorption:Harmful by skin absorption.
 
Inhalation:Harmful by inhalation. May cause irritation of respiratory tract. Inhalation of high vapor concentrations can cause CNS-depression and narcosis.
 
Ingestion:Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
 
Cancer Information:Contains a chemical which is listed by the IARC a a group 2B cancer causing agent (possibly carcinogenic to humans).
 
Target Organ(s): Liver, Kidney, CNS, Respiratory system.
 

Section 3 - Composition/Information on Ingredients

Component CAS # ENIECS REACH Reg. No. Amount
 
Polyester Resin Proprietary 35%
Styrene Monomer 100-42-5 202-851-5 17%
Talc 14807-96-6 238-877-9 42%
Titanium Dioxide 13463-67-7 6%

Section 4 - First Aid Measures

Eye Contact: Immediately flush eyes for at least 15 minutes. Get medical attention.
 
Skin Contact: Wash off with warm water and soap. Remove contaminated clothing and shoes. If skin irritation persists, call a physician. Wash contaminated clothing before reuse.
 
Inhalation: Remove person to fresh air. If signs/symptoms continue, get medical attention. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is labored, administer oxygen. Get medical attention immediately.
 
Ingestion: DO NOT INDUCE VOMITING. ASPIRATION HAZARD. This material may enter the lungs during vomiting. Never give anything by mouth to an unconscious person. GET IMMEDIATE MEDICAL ATTENTION.
 
Medical Conditions Aggravated by Exposure: Anesthesia, headache, respiratory irritation, dermatitis, allergic reactions, nausea, and vomiting.
 

Section 5 - Firefighting Measures

Extinguishing Media: Foam, CO2, Dry chemical, water fog.
 
Fire Fighting Procedures: Wear self contained breathing apparatus to avoid inhalation of vapors.
 
Unusual Fire and Explosion Hazards: Flammable. Vapors may form explosive mixtures with air. Flash back possible over considerable distance. This material may polymerize (react) when its container is exposed to heat (as during a fire). This polymerization increases pressure inside a closed container and may result in the violent rupture of the container.
 

Section 6 - Accidental Release Measures

Steps to be Taken if Material is Released or Spilled: Soak up with inert absorbent material. Remove from surface water (e.g. by skimming or siphoning). Dispose of contaminated material as waste according to item 13.
 
Personal Precautions: Remove all sources of ignition. Evacuate personnel to safe areas. Use personal protective equipment. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas
 
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Soak up with inert absorbent material and dispose of as hazardous waste.
 

Section 7 - Handling and Storage

General Handling: Avoid improper addition of promoter or catalyst.
 
Other Precautions: Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Remove and wash contaminated clothing before re-use. Ensure adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion-proof equipment.
 
Storage: Keep away from heat and sources of ignition. No smoking. Keep away from direct sunlight. Keep containers tightly closed in a cool, well-ventilated place. To ensure maximum stability and maintain optimum resin properties, resins should be stored in closed containers at temperatures below 77°F (25°C).
 

Section 8 - Precautions to Control Exposure / Personal Protection

ComponentSourceTypeValueRemarks

Personal Protective Equipment (PPE):

Eye/Face Protection: Wear safety glasses with side shields and a faceshield or goggles and a faceshield. Ensure that eyewash stations and safety showers are close to the workstation location.
 
Skin Protection: Wear chemical-resistant gloves such as polyvinyl alcohol or Viton. Gloves made of nitrile rubber or polyvinyl chloride (PVC) may be used for splash protection and brief or intermittent contact with styrenated polyester resin.
 
Respiratory Protection: None required if hazards have been assessed and airborne concentrations are maintained below the exposure limits listed in Section 8. Wear an approved air-purifying respirator with organic vapor cartridges and particulate filters where airborne concentrations may exceed exposure limits in Section 8 and/or there is exposure to dust or mists due to sanding, grinding, cutting, or spraying.
 
Hygenic Measures: Wash hands before eating, smoking, or after possible contamination.
 
Other Protection Measures: Wear protective clothing to prevent skin contact. Eye wash stations and safety showers should be available.
 
Engineering Controls: Use general ventilation to maintain airborne concentrations to levels that are below regulatory and recommended occupational exposure limits. Local ventilation may be required during certain operations. Use explosion-proof equipment.
 


Section 9 - Physical and Chemical Properties

Appearance: Gray filler in resin. Pungent odor
 
Color: Gray
 
ph: Not Determined
 
Flash Point: 32°C / 89°F
 
Upper Flammable Limit: 6.1 (Styrene)
 
Lower Flammable Limit: 1.1 (Styrene)
 
Autoignition Temperature: 490°C / 914°F (Styrene)
 
Boiling Point: 146°C / 295°F (Styrene)
 
Vapor Density: Heavier than air
 
Specific Gravity: 1.6
 
Freezing Point: Not Available
 
Melting Point: Not Available
 
Solubility in Water: Slight
 
Evaporation Rate: < 1 (BuAc = 1)
 
Percent Volitiles: 22% by weight
 
Visosity: Not measured

Section 10 - Stability and Reactivity

Stability/Instability: Stable under normal conditions. Stable under recommended storage conditions.
 
Conditions To Avoid: Extreme heat, poor ventilation, exposure to sparks or flames.
 
Incompatible Materials: Avoid contact with strong acids, alkaline materials or oxidants.
 
Hazardous Polymerization: Polymerization can occur. Hazardous polymerization will occur if contaminated with peroxides, metal salts and polymerization catalysts. Product will undergo hazardous polymerization at temperatures above 65°C (150°F ).
 
Hazardous Decomposition Products: CO, CO2, Low molecular weight hydrocarbons, and organic acids.
 

Section 11 - Toxicological Information

Ingestion Toxicity: LD50, Rat: 5,000mg/kg
Skin Absorption:LD50, Rat: >2,000 mg/kh
Inhalation
LC50, Rat: 11.8 mg/l (4 hours)
 
Repeated Dose Toxicity
In humans, styrene may cause a transient decrease in color discrimination and effects on hearing. Repeated or prolonged exposure may cause skin irritation and dermatitis, due to defatting properties of the product. May cause damage to the kidneys, liver, eyes, brain, respiratory system, central nervous system through prolonged or repeated exposure if inhaled.
 
Chronic Toxicity and Carcinogenicity
Styrene: Reasonably anticipated to be human carcinogen.
 
Genetic Toxicity
Styrene has given mixed positive and negative results in a number of mutagenicity tests. Styrene was not mutagenic without metabolic activation but gave negative and positive mutagenic results with metabolic activation.
 
Eye Irritation
Studies indicate that exposures to concentrations of styrene above 200 ppm cause irritation of the eyes. Styrene causes transient moderate eye irritation without corneal involvement.
 
Target Organs
Liver, Kidney, Central nervous system (CNS), Respiratory system
 

Section 12 - Ecological Information

ECOTOXICITY
STYRENE:
Bioconcentration factor (BCF): 13.5 fish
Log Kow: 2.95
 

Section 13 - Disposal Considerations

Disposal Method:
Dispose of in an approved chemical waste landfill or incinerate in accordance with applicable federal, state and local regulations. Do not contaminate lakes, streams, or other water supplies.
 
Container Disposal: Empty containers should be taken for local recycling, recovery or waste disposal.
 

Section 14 - Transport Information

DOT

Proper Shipping Name: Polyester Resin Kit
 
Hazard Class: 3
 
ID Number: UN3269
 
Packing Group: III
 
Additional DOT Shipping Information: Ships as "Limited Quantity" when net capacity of inner packaging is 5 liters (1.3 gallons) or less. (&sec;173.150(b)(2))
 

IMDG (Maritime transport)

IMDG Class: 3
 
UN Number: UN3269
 
Packaging Group: III
 
EMS Number: F-E, S-E
 
Proper Shipping Name: Polyester Resin Kit
 

IATA (Air Transport)

ICAO/IATA Class: 3
 
UN/ID Number: UN3269
 
Air Packaging Group: III
 
Proper Shipping Name: Polyester Resin Kit
 
Additional IATA Shipping Information: Packing Instruction Y370. Not permitted as "Excepted Quantity". "Limited Quantity" when less than 5kg (11 lbs).
 

Section 15 - Regulatory Information

Superfund Amendments and Reathorization Act of 1986 (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312

The following table list hazardous components and the regulatory lists for which they are required to be reported.

Component: Polyester Resin
CAS Number: Proprietary
Amount: 35%

Component: Talc
CAS Number: 14807-96-6
Amount: 42%
Talc is listed with Pennsylvania Right to Know.
Talc is listed with Rhode Island Right to Know.
Talc is listed with Illinois toxic substances discloure to employee act.
Talc is listed with Minnesota Right to Know.

Component:
CAS Number:
Amount: 42%

Component: Styrene Monomer
CAS Number: 100-42-5
Amount: 17%
Styrene Monomer is known to the State of California to cause cancer.
Styrene Monomer is listed with Pennsylvania Right to Know.
Styrene Monomer is listed with Massachusetts Right to Know.
Styrene Monomer is listed with New Jersey Right to Know.
Styrene Monomer is listed with Minnesota Right to Know.

HMIS Rating (Scale 0 - 4)

HEALTH  2  Health = 2
FIRE  2  Fire = 2
PHYSICAL  1  Physical = 1
PERSONAL PROTECTION G Personal Protection = G

NFPA Ratings

 2 
2 1
Health = 2
Fire = 2
Reactivity =1

Section 16 - Other Information

Legend

DISCLAIMER
This Safety Data Sheet (SDS) is prepared in compliance with GHS Hazcom 2012. The information may be based in part on information provided by component suppliers and is believed to be correct as of the date hereof. However, no warranty or merchantability, fitness for any use, or any other warranty is expressed or is to be implied regarding the accuracy of of this data, the results to be obtained from the use of the material, or the hazards connected with such use. Since the information contained herein my be applied under conditions beyond our control and with which we may be unfamiliar, and since data made available subsequent to the date hereof may suggest modification of the information, we assume no responsibility for the result of its use. This information and material is furnished on the condition that the person receiving it shall make his/her own determination as the the suitability of the material for his/her particular purpose and on the condition that he/she assume the risk of his/her use thereof.