Safety Data Sheet

According to GHS (Global Harmonized System) - Hazcom 2012
Date Printed (YYYY-MM-DD): 2017-09-15 

Section 1 - Product and Company Information

Product Name: PlastiFix Liquid
Product Part Number(s): 2520, 2520-L
Recommended Use: Part of a kit for repairing plastic
Revision Date (YYYY-MM-DD):

COMPANY IDENTIFICATION:EMERGENCY TELEPHONE NUMBER
Polyvance24 Hour Emergency ContactChemtrec - 1-800-424-9300 (Outside USA 703-527-3887)
1128 Kirk Rd.Customer Information Number256-638-4103 (7AM - 4PM (CST) M-F)
Rainsville, AL 35986
Information Email: info@polyvance.com

Section 2 - Hazards Identification

Appearance:Colorless liquid
Odor:Acrid, penetrating odor.
Hazard Statement:
 WARNING! . Highly flammable liquid and vapor. Causes mild skin irritation. Causes eye irritation. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life.  

Signal Word:  

WARNING!
Signal Word Hazard:   Flammable Liquid
GHS Physical Hazard PictogramsGHS Health Hazard PictogramsGHS Environmental Hazard Pictograms

Flammable

Irritant
 
Not Applicable

GHS Hazards Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
Physical H225 Highly flammable liquid and vapor
Health H316 Causes mild skin irritation
Health H320 Causes eye irritation
Health H335 May cause respiratory irritation
Health H373 May cause damage to organs through prolonged or repeated exposure
Environmental H402 Harmful to aquatic life
Precautionary Statement:
 Keep away from heat/sparks/open flames/hot surfaces - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with soap and water. Dispose of contents/container to hazardous waste in accordance with local, state or national legislation. Incinereate under approved controlled conditions, using incinerators suitable for the disposal of flammable organics..  

GHS Precautionary Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
Prevention P210 Keep away from heat/sparks/open flames/hot surfaces - No smoking
Prevention P261 Avoid breathing dust/fume/gas/mist/vapours/spray
Prevention P280 Wear protective gloves/protective clothing/eye protection/face protection
Response P302+352 IF ON SKIN: Wash with soap and water
Disposal P501 Dispose of contents/container to hazardous waste in accordance with local, state or national legislation. Incinereate under approved controlled conditions, using incinerators suitable for the disposal of flammable organics.

Potential Health Effects

Eye Contact:Liquid and vapors can cause irritation (tears, blurred vision, redness) and possible corneal damage.
 
Skin Contact:May cause skin irritation (itching and soreness).
 
Skin Absorption:May cause rashes.
 
Skin Sensitization:Can cause skin sensitization.
 
Inhalation:High concentration of vapors is severe irritant to respiratory tract and may cause dizziness, headache and anaesthetic effects. It may cause elevated methmoglobin in the blood.
 
Ingestion:Causes irritation, a burning sensation of the mouth, throat and gastrointestinal tract and abdominal pain, central nervous depression. May cause methemoglobinemia.
 
Birth Defects/Developmental Effects:Developmental toxicity observed in animal tests but only at levels toxic to the mother.
 

Section 3 - Composition/Information on Ingredients

Component CAS # ENIECS REACH Reg. No. Amount
 
Ethylene Glycol Dimethacrylate 97-90-5 0-5%
Methyl Methacrylate Monomer 80-62-6 95-100%

Section 4 - First Aid Measures

Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician.
 
Skin Contact: In case of contact, immediately wash skin with soap and water. Obtain medical attention if blistering occurs or redness persists. Wash contaminated clothing before reuse.
 
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
 
Ingestion: If swallowed, do not induce vomiting. Immediately give two glasses of water. Never give anything by mouth to an unconscious person. Call a physician.
 

Section 5 - Firefighting Measures

Extinguishing Media: Chemical foam, carbon dioxide, dry chemical
 
Fire Fighting Procedures: Wear self contained breathing apparatus, and full protective gear. Use water spray to cool containers.
 
Unusual Fire and Explosion Hazards: Vapors may travel to source of ignition and flash back. Heat can cause polymerization with rapid release of energy whey may rupture container explosively. (Spontaneous polymerization may occur on prolonged storage)
 

Section 6 - Accidental Release Measures

Steps to be Taken if Material is Released or Spilled: Evacuate the area. Eliminate sources of ignition. Use self contained breathing apparatus and protective clothing. Dike and absorb with inert material. Transfer to proper containers for disposal, use non-sparking tools.
 
Personal Precautions: Eliminate sources of ignition. Wear protective gloves and eye/face protection. Avoid breathing vapors. See Section 8
 
Environmental Precautions: Avoid release to the environment. Spillages or uncontrolled discharges into watercourses must be alerted to the appropriate regulatory body.
 

Section 7 - Handling and Storage

General Handling: Do not breathe vapor or mist. Do not get in eyes, on skin or clothing. Wash thoroughly after handling. Keep out of reach of children.
 
Other Precautions: Close container after eash use. Ground container when pouring. Keep away from heat, sparks and flames.
 
Storage: Store in a cool dry place away from heat, sparks, flame and direct sunlight. Store in well-ventilated space. Keep container tightly closed. As long as the bottle is sealed and kept in a cool, dry place, shelf life should be indefinite.
 

Section 8 - Precautions to Control Exposure / Personal Protection

ComponentSourceTypeValueRemarks
Methyl Methacrylate MonomerOSHATWA100 ppm
Methyl Methacrylate MonomerACGIHTWA100 ppmTLV

Personal Protective Equipment (PPE):

Eye/Face Protection: Safety glasses or chemical splash goggles.
 
Skin Protection: Wear protective gloves. For splash protection: Butyl; EN374. For immersion protection: Butyl; 0.7 mm or greater; EN374
 
Respiratory Protection: Wear respiratory protection. Wear suitable pretective equipment if exposure to levels above the occupational exposure limit is likely. A suitable mask with filter type "A" may be appropriate.
 
Hygenic Measures: Wash face and hands thoroughly with soap and water after use and before eating, drinking, smoking or applying cosmetics.
 
Other Protection Measures: Provide eyewash, safety shower and impervious clothing.
 
Engineering Controls: Use good, local explosion-proof ventilation to ensure that the occupational exposure limit is not exceeded.
 


Section 9 - Physical and Chemical Properties

Appearance: Clear Liquid
 
Color: Colorless
 
Odor: Acrid, penetrating odor
 
ph: Not Applicable
 
Flash Point: 11.5° C (52.7° F)
 
Upper Flammable Limit: 12.5
 
Lower Flammable Limit: 2.12
 
Autoignition Temperature: 421°C (790° F)
 
Vapor Pressure: 28 mm Hg @ 20 C (68 F)
 
Boiling Point: 101° C (214° F) at 760 mm Hg
 
Vapor Density: 3.5 @ 60F (Air = 1)
 
Specific Gravity: 0.98 g/ml @ 15.5 C (60 F)
 
Freezing Point: -48° C (-54.4° F)
 
Melting Point: -49° C (-56.2° F)
 
Solubility in Water: 27.6 WT% @ 20 C (68 F)
 
Evaporation Rate: 3.1 (BuAc = 1)
 
Partition Coefficient: 1.38
 
Decomposition Temperature: Not applicable
 
Visosity: Not applicable

Section 10 - Stability and Reactivity

Stability/Instability: Unstable with heat
 
Conditions To Avoid: Temps above 70 F (21 C), ignition sources, oxidizing/reducing agents, peroxides, acids, alkalis, amines, aging & contamination. Material is a strong solvent and can soften paints and rubber.
 
Incompatible Materials: Reducing and oxidizing agents and UV light. Material has strong solvent properties and can soften paint and rubber.
 
Hazardous Polymerization: Can occur.
 
Hazardous Decomposition Products: Mainly oxides of carbon when burned.
 

Section 11 - Toxicological Information

Ingestion Toxicity: 7,900 mg/Kg in rats (very low toxicity by ingestion)
Skin Absorption:LD50: >35,500 mg/Kg in rabbits (very low toxicity by contact)
Inhalation
4 hour LD50: 7093 ppm in rats (very low toxicity by inhalation)
 
Repeated Dose Toxicity
Repeated exposure to high levels produces adverse effects on the heart, lungs, liver and kidneys.
 

Section 12 - Ecological Information

Movement & Partitioning
The product is predicted to have high mobility in soil.
 
Persistence and Degradability
Readily biodegradable.
 
ECOTOXICITY
Low toxicity to fish. Harmful to aquatic invertebrates. Low toxicity to algae.
 
Bioaccumulation:
Product has low potential for bioaccumulation.
 

Section 13 - Disposal Considerations

Disposal Method:
When discarded it is listed as a hazardous waste by the EPA under RCRA U-162 with the reportable quantity of 1000 pounds (40CFR Part 302) Incinerate liquid and diking material after addition of excess inhibitor, in accordance with regulations.
 
Container Disposal: Disposal must be made according to official regulations.
 

Section 14 - Transport Information

DOT

Proper Shipping Name: Methyl Methacrylate Monomer, stabilized
 
Hazard Class: 3.2 (9.2)
 
ID Number: UN1247
 
Packing Group: II
 

IMDG (Maritime transport)

IMDG Class: 3.2
 
UN Number: UN1247
 
Packaging Group: II
 
Proper Shipping Name: Methyl Methacrylate Monomer, stabilized
 
Additional IMDG Shipping Information: Packing instruction P001:
 

IATA (Air Transport)

ICAO/IATA Class: 3
 
UN/ID Number: UN1247
 
Label: Flammable Liquid
 
Air Packaging Group: II
 
Proper Shipping Name: Methyl methacrylate monomer, stabilized
 
Additional IATA Shipping Information: Packing instruction Y341: Inner packaging <0.5L. Total net quantity per package: 1L.

Excepted Quantity (EQ) Code: E2: Maximum net quantity per inner packaging: 30 g / 30 mL.
Maximum net quantity per outer packaging: 500 g / 500 mL
 

Section 15 - Regulatory Information

Superfund Amendments and Reathorization Act of 1986 (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312
Immediate (Acute) Health HazardYes
Delayed (Chronic) Health HazardNo
Fire HazardYes
Reactive HazardYes
Sudden Release of PressureNo

The following table list hazardous components and the regulatory lists for which they are required to be reported.

Component: Methyl Methacrylate Monomer
CAS Number: 80-62-6
Amount: 95-100%
Methyl Methacrylate Monomer is listed with Pennsylvania Right to Know.

HMIS Rating (Scale 0 - 4)

HEALTH  2  Health = 2
FIRE  3  Fire = 3
PHYSICAL  1  Physical = 1
PERSONAL PROTECTION G Personal Protection = G

NFPA Ratings

 3 
2 2
Health = 2
Fire = 3
Reactivity =2

Section 16 - Other Information

Legend
ACGIHAmerican Conference of Governmental Hygenists
CFRCode of Federal Regulations
DFGDeutsche Forschungsgemeinschaft
HMISHazardous Materials Identification System
IARCInternational Agency for Research on Cancer
MAKMaximum Allowable Concentration (German)
MSDSMaterial Safety Data Sheet
NFPANational Fire Protection Association
NIOSHNational Institute for Occupational Safety and Health
OELOccupational Exposure Limit
RCRAResource Conservation and Recovery Act
STELShort Term Exposure Limit
TLVThreshold Limit Value
TWATime Weighted Average

DISCLAIMER
This Safety Data Sheet (SDS) is prepared in compliance with GHS Hazcom 2012. The information may be based in part on information provided by component suppliers and is believed to be correct as of the date hereof. However, no warranty or merchantability, fitness for any use, or any other warranty is expressed or is to be implied regarding the accuracy of of this data, the results to be obtained from the use of the material, or the hazards connected with such use. Since the information contained herein my be applied under conditions beyond our control and with which we may be unfamiliar, and since data made available subsequent to the date hereof may suggest modification of the information, we assume no responsibility for the result of its use. This information and material is furnished on the condition that the person receiving it shall make his/her own determination as the the suitability of the material for his/her particular purpose and on the condition that he/she assume the risk of his/her use thereof.

Safety Data Sheet

According to GHS (Global Harmonized System) - Hazcom 2012
Date Printed (YYYY-MM-DD): 2017-09-15 

Section 1 - Product and Company Information

Product Name: PlastiFix Powder, White
Product Part Number(s): 2531, 2531-L
Recommended Use: To repair broken plastic parts
Revision Date (YYYY-MM-DD):

COMPANY IDENTIFICATION:EMERGENCY TELEPHONE NUMBER
Polyvance24 Hour Emergency ContactChemtrec - 1-800-424-9300 (Outside USA 703-527-3887)
1128 Kirk Rd.Customer Information Number256-638-4103 (7AM - 4PM (CST) M-F)
Rainsville, AL 35986
Information Email: info@polyvance.com

Section 2 - Hazards Identification

Appearance:White powder
Odor:Faint
Hazard Statement:
 Causes mild skin irritation. May cause respiratory irritation. 
GHS Physical Hazard PictogramsGHS Health Hazard PictogramsGHS Environmental Hazard Pictograms
Not Applicable
Not Applicable  
Not Applicable

GHS Hazards Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
Health H316 Causes mild skin irritation
Health H335 May cause respiratory irritation
Precautionary Statement:
 Keep out of reach of children.  

GHS Precautionary Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
General P102 Keep out of reach of children

Potential Health Effects

Eye Contact:May be irritated by gross overexposure, no matter how generated. Keep dust out of eyes.
 
Skin Contact:May be irritated by gross overexposure, no matter how generated. May cause dryness.
 
Skin Absorption:May cause dryness.
 
Inhalation:May irritate eyes, skin and repiratory tract.
 
Ingestion:OSHA classifies the material as Particulates, not otherwise classified.
 

Section 3 - Composition/Information on Ingredients

Component CAS # ENIECS REACH Reg. No. Amount
 
Benzoyl Peroxide 94-36-0 0.5-1.5%
Particulates not otherwise classified 60-100%
Residual monomers NA 0.5-5.0%

Section 4 - First Aid Measures

Eye Contact: Flush with water for 15 minutes, including under eyelids. Get medical help if discomfort persists.
 
Skin Contact: Wash with soap and water. Get medical help if discomfort persists.
 
Inhalation: Remove to fresh air. Get medical help if discomfort persists.
 
Ingestion: Rinse mouth with water. Call doctor if amount was large.
 

Section 5 - Firefighting Measures

Extinguishing Media: Water, carbon dioxide, dry chemical.
 
Fire Fighting Procedures: Avoid extinguishing methods which may generate dust clouds. Water stream can diperse dust into air, producing a fire hazard and possible explosion hazard if exposed to ignition source.
 
Unusual Fire and Explosion Hazards: Polymer dust is combustible. The explosive limits of the polymer particles suspended in air are approximately those of coal dust.
 

Section 6 - Accidental Release Measures

Steps to be Taken if Material is Released or Spilled: Sweep up to avoid slipping hazard. Keep airborne particulates at a minimum when cleaning up spills.
 
Personal Precautions:
 
Environmental Precautions:
 

Section 7 - Handling and Storage

General Handling: Keep out of reach of children.
 
Other Precautions: Use in well ventilated areas. Wear gloves when handling powder.
 
Storage: Store in a cool dry place. Keep container closed to prevent water absorption and contamination.
 

Section 8 - Precautions to Control Exposure / Personal Protection

ComponentSourceTypeValueRemarks
Benzoyl PeroxideOSHAPEL-TWA5 mg/m3
Benzoyl PeroxideACGIHTLV-TWA5 mg/m3
Particulates not otherwise classifiedOSHAPEL-TWA15 mg/m3
Particulates not otherwise classifiedACGIHTLV10 mg/m3

Personal Protective Equipment (PPE):

Eye/Face Protection: Safety glasses of chemical splash goggles.
 
Skin Protection: Normally not necessary, but latex or nitrile gloves are appropriate.
 
Respiratory Protection: Use type for Particulates not otherwise classified, if needed.
 
Hygenic Measures: Wash face and hands thoroughly with soap and water after use and before eating, drinking, smoking, or applying cosmetics.
 
Other Protection Measures: Provide eyewash, safety shower and impervious clothing are recommended.
 
Engineering Controls: Use good, local exhaust.
 


Section 9 - Physical and Chemical Properties

Appearance: Fine powder. Faint odor in bulk.
 
Color: White
 
ph: Not Available
 
Flash Point: 580F
 
Upper Flammable Limit: Not Available
 
Lower Flammable Limit: Not Available
 
Autoignition Temperature: Not Available
 
Vapor Pressure: Not Available
 
Boiling Point: Not Available
 
Vapor Density: Not Available
 
Specific Gravity: 1.25
 
Freezing Point: Solid at room temperature.
 
Melting Point: Not Available
 
Solubility in Water: Insoluble
 
Evaporation Rate: Not Available
 
Partition Coefficient: Not Available
 
Decomposition Temperature: Not Available
 
Visosity: Not Available

Section 10 - Stability and Reactivity

Stability/Instability: Stable
 
Conditions To Avoid: Heating above 464 F (240 C)
 
Incompatible Materials: Strong oxidizing agents.
 
Hazardous Polymerization: Will not occur
 
Hazardous Decomposition Products: Methacrylate monomer and oxides of carbon when burned.
 

Section 11 - Toxicological Information

Ingestion Toxicity: Not Available
Skin Absorption:Not Available
Inhalation
Not Available
 

Section 12 - Ecological Information

ECOTOXICITY
Not Available
 

Section 13 - Disposal Considerations

Disposal Method:
Dispose in a landfill or incinerate according to Federal, State and Local regulations.
 
Container Disposal: Reuse of empty drums or containers is not recommended. Employees should be advised of the potential hazards, due to residual material associated with empty containers. It is our policy to discourage the reuse of empty containers and to dispose of all empty containers properly in accordance with Federal, State and Local regulations.
 

Section 14 - Transport Information

DOT

Additional DOT Shipping Information: Not regulated as a hazardous material or dangerous goods for transportation by this agency.
 

IMDG (Maritime transport)

Additional IMDG Shipping Information: Not regulated as a hazardous material or dangerous goods for transportation by this agency.
 

IATA (Air Transport)

Additional IATA Shipping Information: Not regulated as a hazardous material or dangerous goods for transportation by this agency.
 

Section 15 - Regulatory Information

Superfund Amendments and Reathorization Act of 1986 (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312

The following table list hazardous components and the regulatory lists for which they are required to be reported.

Section 16 - Other Information

Legend
ACGIHAmerican Conference of Governmental Hygenists
CFRCode of Federal Regulations
DFGDeutsche Forschungsgemeinschaft
HMISHazardous Materials Identification System
IARCInternational Agency for Research on Cancer
MAKMaximum Allowable Concentration (German)
MSDSMaterial Safety Data Sheet
NFPANational Fire Protection Association
NIOSHNational Institute for Occupational Safety and Health
OELOccupational Exposure Limit
RCRAResource Conservation and Recovery Act
STELShort Term Exposure Limit
TLVThreshold Limit Value
TWATime Weighted Average

DISCLAIMER
This Safety Data Sheet (SDS) is prepared in compliance with GHS Hazcom 2012. The information may be based in part on information provided by component suppliers and is believed to be correct as of the date hereof. However, no warranty or merchantability, fitness for any use, or any other warranty is expressed or is to be implied regarding the accuracy of of this data, the results to be obtained from the use of the material, or the hazards connected with such use. Since the information contained herein my be applied under conditions beyond our control and with which we may be unfamiliar, and since data made available subsequent to the date hereof may suggest modification of the information, we assume no responsibility for the result of its use. This information and material is furnished on the condition that the person receiving it shall make his/her own determination as the the suitability of the material for his/her particular purpose and on the condition that he/she assume the risk of his/her use thereof.