Safety Data Sheet

According to GHS (Global Harmonized System) - Hazcom 2012
Date Printed (YYYY-MM-DD): 2018-01-31 

Section 1 - Product and Company Information

Product Name: PlastiFix High Performance Adhesive
Product Part Number(s):
Recommended Use: For repairing automotive plastics
Revision Date (YYYY-MM-DD):

COMPANY IDENTIFICATION:EMERGENCY TELEPHONE NUMBER
Polyvance24 Hour Emergency ContactChemtrec - 1-800-424-9300 (Outside USA 703-527-3887)
1128 Kirk Rd.Customer Information Number256-638-4103 (7AM - 4PM (CST) M-F)
Rainsville, AL 35986
Information Email: info@polyvance.com

Section 2 - Hazards Identification

Appearance:Milky white liquid
Odor:Strong, irritating odor
Hazard Statement:
 Highly flammable liquid and vapor. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. 
Signal Word Hazard:   Highly flammable liquid and vapor
GHS Physical Hazard PictogramsGHS Health Hazard PictogramsGHS Environmental Hazard Pictograms

Flammable

Irritant
 
Not Applicable

GHS Hazards Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
Physical H225 Highly flammable liquid and vapor
Health H302 Harmful if swallowed
Health H312 Harmful in contact with skin
Health H314 Causes severe skin burns and eye damage
Health H315 Causes skin irritation
Health H317 May cause an allergic skin reaction
Health H335 May cause respiratory irritation
Precautionary Statement:
 Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces - No smoking. Wear respiratory protection. IF ON SKIN: Wash with soap and water. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. 

GHS Precautionary Statement Codes for This Product

Statement
Type
Statement
Code
Statement Text
General P102 Keep out of reach of children
Prevention P210 Keep away from heat/sparks/open flames/hot surfaces - No smoking
Prevention P284 Wear respiratory protection
Response P302+352 IF ON SKIN: Wash with soap and water
Response P304+341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing
Response P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing

Potential Health Effects

Section 3 - Composition/Information on Ingredients

Component CAS # ENIECS REACH Reg. No. Amount
 
Methacrylic Acid 79-41-4 201-204-4 20 - 30%
Methyl Methacrylate 80-62-6 201-297-1 50 - 70%

Section 4 - First Aid Measures

Eye Contact: Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. Contact physician if irritation persists.
 
Skin Contact: Remove affected person from source of contamination. Wash skin thoroughly with soap and water for several minutes. Contact physician if irritation persists.
 
Inhalation: Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Contact physician if discomfort continues.
 
Ingestion: Do not induce vomiting. Drink plenty of water. Get medical attention.
 

Section 5 - Firefighting Measures

Extinguishing Media: Extinguish with foam, carbon dioxide or dry powder.
 
Fire Fighting Procedures: Keep up-wind to avoid fumes. Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-figthers Self contained breathing apparatus and full protective clothing must be worn in case of fire.
 

Section 6 - Accidental Release Measures

Steps to be Taken if Material is Released or Spilled:
 
Personal Precautions: Highly flammable Warn everybody of potential hazards and evacuate if necessary. Remove sources of ignition. Provide adequate ventilation. Avoid contact with skin and eyes. Avoid inhalation of spray mist and contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet.
 
Environmental Precautions: Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.
 

Section 7 - Handling and Storage

General Handling: Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. Avoid contact with skin and eyes. Take precautionary measures against static discharges. Storage tanks and other containers must be grounded. Do not smoke, use open fire or other sources of ignition. Observe good chemical hygiene practices.
 
Other Precautions:
 
Storage: Store in tightly closed original container in a dry, cool and well-ventilated place.
 

Section 8 - Precautions to Control Exposure / Personal Protection

ComponentSourceTypeValueRemarks

Personal Protective Equipment (PPE):

Eye/Face Protection: Wear approved chemical safety goggles where eye exposure is reasonably probable.
 
Skin Protection: Use protective gloves made of Rubber or plastic. Wear apron or protective clothing in case of contact.
 
Respiratory Protection: If ventilation is insufficient, suitable respiratory protection must be provided. Chemical respirator with organic vapour cartridge.
 
Hygenic Measures: Keep away from food, drink and animal feeding stuffs. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Do not eat, drink or smoke when using the product. Change work clothing daily before leaving work place.
 
Engineering Controls: Provide adequate general and local exhaust ventilation.
 


Section 9 - Physical and Chemical Properties

Appearance: Paste
 
ph: Not Determined
 
Flash Point: 10°C (50°F)
 
Upper Flammable Limit: 12.5%
 
Lower Flammable Limit: 2.1%
 
Autoignition Temperature: No data available
 
Vapor Pressure: 28 mmHg 20
 
Boiling Point: 101°C (214°F)
 
Vapor Density: >1
 
Specific Gravity: 1.03 at 20°C (68°F)
 
Freezing Point: Not Available
 
Melting Point: Not Available
 
Solubility in Water: 15 g/L (Methyl Methacrylate)
 
Evaporation Rate: 3 (butyl acetate = 1)
 
Partition Coefficient: log Pow: 1.38 (Methyl Methacrylate)
 
Decomposition Temperature: No data available
 
Visosity: 40,000 - 60,000 cps

Section 10 - Stability and Reactivity

Stability/Instability: Stable under normal temperature conditions and recommended use. May polymerise.
 
Conditions To Avoid: Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolonged periods of time. Avoid exposure to high temperatures or direct sunlight. Heating will generate vapours which may form explosive vapour/air mixtures.
 
Incompatible Materials: Avoid contact with oxidisers or reducing agents. Bases, alkalis (inorganic). Bases, alkalis (organic).
 
Hazardous Polymerization: May polymerize.
 
Hazardous Decomposition Products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours
 

Section 11 - Toxicological Information

Ingestion Toxicity: LD 50 METHYL METHACRYLATE 7872 mg/kg (oral rat) LD 50 METHACRYLIC ACID 1060 mg/kg (oral rat)
Inhalation
LC 50 METHYL METHACRYLATE 7093 ppm/4h (inh-rat)
 
Sensitization
May cause sensitisation by skin contact. Risk of sensitisation or allergic reactions among sensitive individuals.
 
Eye Irritation
Irritating to eyes. Risk of corneal damage.
 
Target Organs
May cause damage to the liver and kidneys. Central nervous system Respiratory system, lungs.
 

Section 12 - Ecological Information

Movement & Partitioning
Do not discharge into drains, water courses or onto the ground.
 
ECOTOXICITY
Avoid release to the environment.
 

Section 13 - Disposal Considerations

Disposal Method:
Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority. When handling waste, consideration should be made to the safety precautions applying to handling of the product.
 

Section 14 - Transport Information

DOT

Proper Shipping Name: Adhesives containing flammable liquid
 
Hazard Class: 3
 
ID Number: UN1133
 
Packing Group: II
 

IMDG (Maritime transport)

IMDG Class: 3
 
UN Number: UN1133
 
Packaging Group: II
 
Maritime Marine Pollutant: 14.6
 
Proper Shipping Name: Adhesives containing flammable liquid
 
Additional IMDG Shipping Information: Environmentally Hazardous Substance/Marine Pollutant No. 14.6. Special precautions for user EMS F-E, S-D
 

IATA (Air Transport)

ICAO/IATA Class: 3
 
UN/ID Number: UN1133
 
Air Packaging Group: II
 
Proper Shipping Name: Adhesives containing flammable liquid
 

Section 15 - Regulatory Information

Superfund Amendments and Reathorization Act of 1986 (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312

The following table list hazardous components and the regulatory lists for which they are required to be reported.

Component: Methacrylic Acid
CAS Number: 79-41-4
Amount: 1 - 10%
Methacrylic Acid is known to the State of California to cause cancer.
Methacrylic Acid is listed with Pennsylvania Right to Know.
Methacrylic Acid is listed with Rhode Island Right to Know.
Methacrylic Acid is listed with New Jersey Right to Know.
Methacrylic Acid is listed with Minnesota Right to Know.

Component: Methyl Methacrylate
CAS Number: 80-62-6
Amount: 30 - 60%
Methyl Methacrylate is listed in SARA 313
Methyl Methacrylate is listed with Pennsylvania Right to Know.
Methyl Methacrylate is listed with Massachusetts Right to Know.

HMIS Rating (Scale 0 - 4)

HEALTH  2  Health = 2
FIRE  3  Fire = 3
PHYSICAL  3  Physical = 3
PERSONAL PROTECTION H Personal Protection = H

NFPA Ratings

 3 
2 2
Health = 2
Fire = 3
Reactivity =2

Section 16 - Other Information

Legend

DISCLAIMER
This Safety Data Sheet (SDS) is prepared in compliance with GHS Hazcom 2012. The information may be based in part on information provided by component suppliers and is believed to be correct as of the date hereof. However, no warranty or merchantability, fitness for any use, or any other warranty is expressed or is to be implied regarding the accuracy of of this data, the results to be obtained from the use of the material, or the hazards connected with such use. Since the information contained herein my be applied under conditions beyond our control and with which we may be unfamiliar, and since data made available subsequent to the date hereof may suggest modification of the information, we assume no responsibility for the result of its use. This information and material is furnished on the condition that the person receiving it shall make his/her own determination as the the suitability of the material for his/her particular purpose and on the condition that he/she assume the risk of his/her use thereof.